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1,3,6-Hexanetrinitrile is an important intermediate in many industrial applications, for example, tricarboxyl groups that can be used as detergents can be obtained by hydrolysis. The corresponding hydrogenation of trinitrile produces 1,3,6-triaminohexane, which can then be gasified in another step to form 1,3,6-triisocyanatohexane. The compound is used as an important basic building block in polyurethane (PU) chemistry, for example in the preparation of polyurethane adhesives or polyurethane coatings. 1,3,6-Hexanetrinitrile is an important electrolyte additive, the composition of the electrolyte limits the application of positive and negative electrode materials in high voltages, and traditional organic carbonates (such as chain carbonate DEC, DMC, EMC and cyclic carbonate PC, EC, etc.) will decompose at high voltages [2,3Chemicalbook]. Therefore, the development of new organic solvents with wide electrochemical window, high solubility and low toxicity to lithium salts has become one of the focuses of the development of high-voltage electrolytes. Nitrile organic solvents usually have a wide electrochemical window, high anode stability, low viscosity and high boiling point and other excellent characteristics [4], in addition, the organic solvent decomposition products containing nitrile groups are generally carboxylates, aldehydes or corresponding organic amines, and there will be no highly toxic CN- ions during use [5~7]. Nitrile solvents have a wide electrochemical window and are promising new organic solvents. However, from the perspective of the electrochemical performance of lithium-ion batteries, nitrile solvents still have compatibility problems with the negative electrode, and the formation of a blending system with carbonate solvents or the addition of blended salt LiBOB can improve this problem to a certain extent
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Pharma Sources Insight JANUARY 2024
